New Synthesis of the (3Z,6Z,9S,10R)-Isomers of 9,10-Epoxy-3,6-henicosadiene and 9,10-Epoxy-1,3,6-henicosatriene, Pheromone Components of the Female Fall Webworm Moth, Hyphantria cuneaPheromone Synthesis, Part 230. For Part 229, see Mori, K., Eur. J. Org. Chem., in press
نویسندگان
چکیده
(3Z,6Z,9S,10R)-9,10-Epoxy-3,6-henicosadiene (1) and (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-henicosatriene (5), pheromone components of the female fall webworm moth (Hyphantria cunea Drury), were synthesized by starting from (2S,3R)-2,3-epoxy-4-t-butyldimethylsilyloxy-1-butanol (8). Epoxide 8 was prepared by employing lipase-catalyzed asymmetric acetylation of ( )-8 as the key optical resolution step.
منابع مشابه
Synthesis of the Four Stereoisomers of 7-Acetoxy-15-methylnonacosane, a Component of the Female Sex Pheromone of the Screwworm Fly, Cochliomyia hominivoraxPheromone Synthesis, Part 227. For Part 226, see Muto, S., Bando, M., and Mori, K., Eur. J. Org. Chem., 1946--1952 (2004)
Insect Pheromone and Traps Division, Fuji Flavor Co., Ltd., Midorigaoka 3-5-8, Hamura-shi, Tokyo 205-8503, Japan Graduate School of Life Sciences, Tohoku University, Tsutsumidori-Amamiya 1-1, Aoba-ku, Sendai 981-8555, Japan U.S. Department of Agriculture, Agricultural Research Service, Midwest Livestock Insect Research Unit, Lincoln, Nebraska 68583, U.S.A. U.S. Department of Agriculture, Agricu...
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